Product ID:CARTRIDGE FOR POWER DEVICE, DPE000093
MSDS Date:08/25/1995
FSC:1377
NIIN:00N048368
MSDS Number: CDZLG

OLIN CORP

120 LONG RIDGE RD
STAMFORD, CT 06904
US

Emergency Phone: 800-654-6911

Info Phone: 203-356-3449

Cage: 8X135

OLIN CORP CHEMICALS GROUP

STAMFORD, CT 06904 US

Telephone: 203-356-3449,CHEMTREC 800-242-9300

Cage: 53084

ADDNL EFTS WOULD BE SIMILAR TO THOSE IN ACUTE INHAL.

RTECS: 9999999ZZ

INGEST OR HAVE BEEN REPORTED EXCEPT FOR THOSE IN

RTECS: 9999999ZZ

PROD CNTNS DETECTABLE AMTS OF CHEM(S)

RTECS: 9999999ZZ

LEAD APPEARS ON NAVY

RTECS: 9999999ZZ

APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST

RTECS: 9999999ZZ

FLAMES IN HAZ AREA. PLACE IN PROPER DOT CNTNR

RTECS: 9999999ZZ

RESPONSIBILITY TO DISP OF UNUSED MATL,

RTECS: 9999999ZZ

& FEDERAL LAWS & REGULATIONS REGARDING TREATMENT,

RTECS: 9999999ZZ

SHELLCASE (CONSISTING OF INGS 2 & 3)

RTECS: 9999999ZZ

Fraction By Weight: 75-85%

OSHA PEL N/K

ACGIH TLV: N/K

COPPER (SARA 313) (CERCLA)

CAS: 7440-50-8

RTECS: GL5325000

Fraction By Weight: 50-65%

OSHA PEL 0.1MG/M3 FUME;1 DUST

ACGIH TLV: 0.2 MG/M3 FUME

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ZINC (SARA 313) (CERCLA)

CAS: 7440-66-6

RTECS: ZG8600000

Fraction By Weight: 15-30%

OSHA PEL 5 MG/M3 (MFR)

ACGIH TLV: 10 MG/M3 (MFR)

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PROPELLANT (CONSISTING OF INGS 5 - 7)

Fraction By Weight: 7-13%

OSHA PEL N/K

ACGIH TLV: N/K

NITROCELLULOSE

CAS: 9004-70-0

RTECS: QW0970000

Fraction By Weight: 7-13%

OSHA PEL N/K

ACGIH TLV: N/K

NITROGLYCERIN (NG) (SARA 313) (CERCLA)

CAS: 55-63-0

RTECS: QX2100000

Fraction By Weight: 0.5-2%

OSHA PEL 0.2 MG/M3, S, C

ACGIH TLV: 0.05 PPM, S

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

PHTHALIC ACID, DIBUTYL ESTER; (DIBUTYL PHTHALATE) (SARA

CAS: 84-74-2

RTECS: TI0875000

Fraction By Weight: 0.5-2%

OSHA PEL 5 MG/M3

ACGIH TLV: 5 MG/M3

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

PRIMING MIX/PRIMER (CONSISTING OF INGS 9 - 12)

RTECS: 9999999ZZ

Fraction By Weight: 4-7%

OSHA PEL N/K

ACGIH TLV: N/K

COPPER (SARA 313) (CERCLA)

CAS: 7440-50-8

RTECS: GL5325000

Fraction By Weight: 0-5%

OSHA PEL 0.1MG/M3 FUME;1 DUST

ACGIH TLV: 0.2 MG/M3 FUME

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ZINC (SARA 313) (CERCLA)

CAS: 7440-66-6

RTECS: ZG8600000

Fraction By Weight: 0-2%

OSHA PEL 5 MG/M3 (MFR)

ACGIH TLV: 10 MG/M3 (MFR)

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LEAD STYPHNATE

CAS: 15245-44-0

Fraction By Weight: 0-1%

OSHA PEL 0.05 MG/M3 (MFR)

ACGIH TLV: 0.05 MG/M3 (MFR)

2)

CAS: 10022-31-8

RTECS: CQ9625000

Fraction By Weight: 0-1%

OSHA PEL 5 MG/M3 (BA)

ACGIH TLV: 2 MG/M3 (BA)

NON-HAZARDOUS INGREDIENTS; (PAPER WAD)

Fraction By Weight: 0.5-2%

OSHA PEL N/K

ACGIH TLV: N/K

STARTS AT FOREHEAD PRECEDED BY SENSATION OF WARMTH &

RTECS: 9999999ZZ

DERM EXPOS TO

RTECS: 9999999ZZ

UPON REMOVAL OF MATL W/OUT PERM DMG. ADDNL EFTS

RTECS: 9999999ZZ

OCCUR W/INFLAMM OF CONJ. ANY EFT WOULD NOT RSLT IN

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SM AMT OF INHALABLE PARTICLES MAY BE
CREATED WHEN CARTRIDGE IS FIRED. PARTICLES FROM FIRING MAY BE
HARMFUL IF SWALLOWED. PROD IS COMPOSED OF FINISHED CARTRIDGE &
PROPELLANT IS COMPLETELY SEALED. IT IS JUDGED THAT PHYSICAL NATURE
OF PROD, LOW PERCENTAGE OF PROPELLANT IN PROD & ITS USE WOULD
PRECLUDE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:INHAL, SKIN ABSORPTION/INGEST OF
SUFFICIENT AMT OF PROPELLANT & DEVEL OF THESE ACUTE &/OR CHRONIC
SYMPS. IT IS JUDGED THAT EYE EFTS WOULD NOT OCCUR BECAUSE OF
PHYSICAL NATURE OF PROD & LOW PE RCENTAGE OF PROPELLANT IN PROD &
ITS USE. ACUTE:INHAL:INHAL OF PROPELLANT IS IRRIT TO NOSE, MOUTH,
THROAT & (SUPP DATA)
Medical Cond Aggravated by Exposure:NONE KNOWN OR REPORTED.

First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:IMMEDIATELY FLUSH
W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM
MD . SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD .

Extinguishing Media:WATER SPRAY NOTE:DO NOT FIGHT FIRE IF FIRE REACHES
CARGO. USE WATER FROM UNMANNED STATION.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
EVACUATE ALL PERS INCL EMER RESPONSE PERS FROM AREA FOR 1500 FT
(1/2 MILE) IN ALL DIRECTIONS IF FIRE (SUPP DATA)
Unusual Fire/Explosion Hazard:EXPLOSIVE.

Spill Release Procedures:FOR ALL TRANSPORTATION ACCIDENTS, CALL
CHEMTREC (800-424-9300). PROD DOES REPRESENT EXPLO HAZ WHEN
INVOLVED IN FIRE/EXPOS TO HEAT, FRICTION, SHOCK, ETC. REMOVE ALL
SOURCES OF IGNIT. LAND SPILL. SHUT O FF ALL IGNIT SOURCES, NO
FLARES, SMOKING/ (ING 23)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT TAKE INTERNALLY. AVOID CONTACT
W/SKIN, EYES & CLOTHING. STORE IN COOL, DRY, WELL VENTILATED PLACE,
AWAY FROM ALL SOURCES OF IGNITION.
Other Precautions:DO NOT SUBJECT TO MECHANICAL SHOCK. SHELF LIFE
LIMITATIONS: 25-30 YEARS. INCOMPATIBLE MATERIALS FOR STORAGE OR
TRANSPORT: ACIDS, CLASS A & B EXPLOSIVES & OXIDIZERS.

Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . NONE REQUIRED FOR NORMAL HANDLING.
Ventilation:NONE BEYOND NORMAL VENTILATION.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . NONE NORMALLY REQUIRED.
Work Hygienic Practices:UPON CONTACT W/SKIN OR EYES, WASH OFF W/WATER.
Supplemental Safety and Health
FIRE FIGHT PROC:REACHES CARGO. CNDTNS(STAB):PLACED IN HIGH RADIO
FREQUENCY ENERGY FIELD (RADAR STATIONS). EFTS OF OVEREXP:LUNGS.
DILATION OF BLOOD VESSELS W/DROP IN BLOOD PRESS & HDCH, CYANOSIS &
MENT AL CONFUSN MAY RSLT FROM NITROGLYCERIN.HDCH MAY BE SEV & CAN
REMAIN FOR FEW HRS TO SEVERAL DAYS. IT TYPICALLY (ING 14)

Appearance and Odor:CYLINDRICAL, BRASS CARTRIDGE; NO ODOR.

Stability Indicator/Materials to Avoid:YES
ACIDS & CAUSTICS.
Stability Condition to Avoid:MECH SHOCK/IMPACT & ELEC(STATIC)
DISCHARGE. CARTRIDGE MAY DETONATE IF CASE IS PUNCTURED/SEV DMGD.
CARTRIDGES (SUPP DATA)
Hazardous Decomposition Products:NITROGEN OXIDES, CARBON MONOXIDE,
CARBON DIOXIDE, LEAD OXIDES, LEAD DUST/FUME.

Waste Disposal Methods:IF PROD BECOMES WASTE, IT MEETS CRITERIA OF HAZ
WASTE AS DEFINED UNDER 40 CFR 261 & 268 & MUST BE MANAGED
ACCORDINGLY - EPA HAZ WASTE #D003. OTHER:DEACTIVATION. CARE MUST BE
TAKEN TO PVNT ENVIRON CONT AM FROM USE OF MATL. USER OF MATL HAS
(ING 24)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.